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■Chemist JOTARO 中崎城太郎の研究課題
Tetrahedron Letters
vol.40, pp.8819-8822 (1999).
New Synthesis of 2-[1,3-Dithiol-2-ylidene]
-5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiins
with Formyl Group
on
Fused-Benzene, [1,4]Dithiin, or Thiophene Ring
縮環したベンゼン環、[1,4]ジチイン環、チオフェン環上に
ホルミル基を有する
2-[1,3-Dithiol-2-ylidene]-5,6-dihydro
-1,3-dithiolo[4,5-b][1,4]dithiin
の新たな合成法
Yoshihiro Ishikawa, Tomoko Miyamoto, Asami Yoshida, Yuzo Kawada
Department of Chemistry, Faculty of Science, Ibaraki University
石川佳寛、宮本朋子、吉田麻美、川田勇三
茨城大学理学部化学科
Jotaro Nakazaki, Akira Izuoka, Tadashi Sugawara
Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo
中崎城太郎、泉岡 明、菅原 正
東京大学大学院総合文化研究科・広域科学専攻・相関基礎科学系
As novel TTF-based annelated donors, 2-[1,3-dithiol-2-ylidene]-5,6-dihydro-1,3-dithiolo[4,5-b][1,4]dithiins with a formyl group on fused benzene, [1,4]-dithiin, or thiophene ring, respectively, were prepared using Diels-Alder or an intramolecular aldol reaction.
[↑有機磁性導体の概要]
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